REDUCTIVE DEHALOGENATION OF ALPHA-HALOKETONES PROMOTED BY HYDROIODIC ACID AND WITHOUT SOLVENT

被引：15

作者：

PENSO, M ^{[1
]}

MOTTADELLI, S ^{[1
]}

ALBANESE, D ^{[1
]}

机构：

[1] UNIV MILAN,DIPARTIMENTO CHIM ORGAN & IND,I-20133 MILAN,ITALY

来源：

SYNTHETIC COMMUNICATIONS | 1993年 / 23卷 / 10期

关键词：

D O I：

10.1080/00397919308011227

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Several alpha-haloketones have been transformed into the corresponding ketones by reaction with aqueous 57% HI, without solvent. The products are obtained in nearly quantitative yields and with high purity (>99%) even in the case of sterically hindered starting materials.

引用

页码：1385 / 1391

页数：7

共 26 条

[1] REDUCTIVE DEHALOGENATION OF ALPHA-HALOKETONES BY SODIUM-IODIDE AND METAL-SALTS
ONO, A
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SYNTHESIS-STUTTGART, 1986, (07): : 570 - 571
[2] BIS(TRIPHENYLSTANNYL)TELLURIDE - A MILD AND EFFICIENT REDUCTIVE DEHALOGENATION REAGENT FOR ALPHA-HALOKETONES
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TETRAHEDRON LETTERS, 1991, 32 (12) : 1545 - 1548
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SHIRAI, Y
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ONO, A
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TETRAHEDRON LETTERS, 1992, 33 (43) : 6449 - 6452
[6] DEHALOGENATION OF ALPHA-HALOKETONES AND VIC-DIBROMIDES WITH NICKEL BORIDE
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ONO, A
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SYNTHESIS-STUTTGART, 1987, (04): : 406 - 407
[8] DEHALOGENATION OF ALPHA-HALOKETONES VIA ALPHA-OXOCARBONIUM IONS TO STABLE OXONIUM SALTS
BEGUE, JP
CHARPENT.M
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 1971, 10 (05) : 327 - &
[9] beta-Diketone synthesis by reaction of alpha-haloketones with acid chlorides or acid anhydrides promoted by samarium triiodide
Ying, TK
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SYNTHETIC COMMUNICATIONS, 1996, 26 (15) : 2905 - 2909
[10] REACTIONS OF CYCLIC ESTERS OF PHOSPHOROUS ACID WITH ALPHA-HALOKETONES
PUDOVIK, AN
KOCHETKO.VI
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JOURNAL OF GENERAL CHEMISTRY USSR, 1961, 31 (08): : 2475 - &

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