Redox-Mediator Oxidation of Aliphatic Alcohols to Carboxylic Acids on Nickel Hydroxide and Cobaltoxide Porous Hydrophobized Electrodes

被引：0
|
作者：
Chaenko, Natalya V. [1 ,2 ]
Kornienko, Vasily L.
Kornienko, Galina V. [1 ]
机构：
[1] RAS, SB, Inst Chem & Chem Technol, 42 K Marx St, Krasnoyarsk 660049, Russia
[2] Siberian Fed Univ, Krasnoyarsk 660041, Russia
来源：
JOURNAL OF SIBERIAN FEDERAL UNIVERSITY-CHEMISTRY | 2009年 / 2卷 / 01期
关键词：
Oxidation; redox-mediators; aliphatic alcohols; nickel hydroxide; porous hydrophobized anodes; carboxylic acids; cobalt oxide;
D O I：
暂无
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Redox-mediator oxidation of aliphatic alcohols to carboxylic acids on nickel hydroxide (ONE) and cobalt oxide (OCE) porous hydrophobized electrodes in alkaline medium was studied. A method of producing porous hydrophobized nickel hydroxide electrodes developed. Kinetics and selectivity of the indirect oxidation of isobutyl, isoamyl, hexyl , nonanoic and undecenol alcohols to the corresponding carboxylic acids are studied. Studies have shown the efficiency of application of porous hydrophobized oxide-nickel electrodes for redox-mediator oxidation of aliphatic alcohols with long carbon chain C6 - C9 in the potential window 0.7 -0.9 V(vs. SCE).
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页码：64 / 70
页数：7
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