Indirect electrochemical oxidation of aliphatic alcohols to carboxylic acids by active oxygen forms in aqueous media

被引：10
|
作者：
Chaenko, N. V. [1 ,2 ]
Kornienko, G. V. [1 ]
Kosheleva, A. M. [1 ]
Maksimov, N. G. [1 ]
Kornienko, V. L. [1 ]
机构：
[1] Russian Acad Sci, Siberian Branch, Inst Chem & Chem Technol, Krasnoyarsk, Russia
[2] Siberian Fed Univ, Krasnoyarsk, Russia
来源：
RUSSIAN JOURNAL OF ELECTROCHEMISTRY | 2011年 / 47卷 / 10期
基金：
俄罗斯基础研究基金会;
关键词：
indirect electrooxidation; aliphatic alcohols; active oxygen forms; ORGANIC-COMPOUNDS;
D O I：
10.1134/S102319351110003X
中图分类号：
O646 [电化学、电解、磁化学];
学科分类号：
081704 ;
摘要：
Indirect electrochemical oxidation of aliphatic alcohols (butanol, hexanol, nonanol, decanol) to the corresponding carboxylic acids by active oxygen forms (AOFs) generated in situ in electrochemical cells from O-2, H2O2, H2O is carried out in aqueous electrolyte using anodes of lead dioxide, a nickel oxide electrode, and boron-doped diamond electrode (BDDE). It is found that selectivity of the process of indirect electrosynthesis of carboxylic acids depends on the chemical nature of the anode material and structure of the initial alcohol and is determined by the conditions of AOF generation. Coupled electrosynthesis with simultaneous in situ generation of AOFs on the cathode and anode occurs more effectively with formation of the corresponding carboxylic acids.
引用
收藏
页码：1146 / 1151
页数：6
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