ANSA-TITANOCENE AND ZIRCONOCENE COMPLEXES WITH ASYMMETRICALLY SUBSTITUTED CARBON BRIDGES

被引:31
|
作者
HERRMANN, GS
ALT, HG
RAUSCH, MD
机构
[1] UNIV BAYREUTH,ANORGAN CHEM LAB,UNIV STR 30,W-8580 BAYREUTH,GERMANY
[2] UNIV MASSACHUSETTS,DEPT CHEM,AMHERST,MA 01003
关键词
D O I
10.1016/0022-328X(91)86212-9
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
The di-anions of the general type [(C5H4)CHR(Cp')]2- (R = Me, (t)Bu; Cp' = C5H4, C9H6, C13H8) react with MCI4 (M = Ti, Zr) in solution to give the complexes [(C5H4)CHR(Cp')]MCl2. These complexes were characterized by H-1 and C-13 NMR spectroscopy.
引用
收藏
页码:C5 / C9
页数:5
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