PARTIAL HYDROGENATION - FROM ANTHRACENE TO CORONENE

被引：38
|
作者：
YALPANI, M
KOSTER, R
机构：
[1] Max-Planck-Institut Für Kohlenforschung, Mülheim An Der Ruhr, D-4330
来源：
CHEMISCHE BERICHTE | 1990年 / 123卷 / 04期
关键词：
Polycyclic arenes / Hydrogenation / Borane catalysts / Hydroarenes / Tetraalkyldiboranes(6);
D O I：
10.1002/cber.19901230412
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Reduktion kondensierter Arene mit ‐Boranen. – Partielle Hydrierung: Anthracen bis Coronen Tetrapropyldiboran(6) (TPDB) katalysiert die Hydrierung polycyclisher Arene [z. B. Anthracen (A), Tetracen (TET), Pyren (PY), Perylen (PER) oder Coronen (C)] unter Wasserstoff‐Druck bei 200°C. In einigen Fällen können sehr hohe Ausbeuten an Hydroarenen erzielt werden [z. B. Tetrahydroanthracen (4H‐A), Octahydroanthracen (8H‐A), Dodecahydrotetracen (12H‐TET), Tetrahydropyren (4H‐PY), Hexahydroperylen (6H‐PER) oder Hexahydrocornen (6H‐C)]. Neben unterschiedlichen kleinen Mengen an Perhydroarenen bilden sich nach langer Reaktionszeit aus sämtlichen Arenen auch C – C‐Spaltungsprodukte. Copyright © 1990 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim
引用
收藏
页码：719 / 724
页数：6
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