STRUCTURE PROPERTY RELATIONS IN PHOTOINITIATORS OF POLYMERIZATION .4. COPOLYMERIZABLE PHOTOINITIATORS

被引：8
|
作者：
RUHLMANN, D [1 ]
ZAHOUILY, K [1 ]
FOUASSIER, JP [1 ]
机构：
[1] ECOLE NATL SUPER CHIM,CNRS,UNITE RECH,PHOTOCHIM GEN LAB,3 RUE A WERNER,F-68093 MULHOUSE,FRANCE
来源：
EUROPEAN POLYMER JOURNAL | 1992年 / 28卷 / 09期
关键词：
D O I：
10.1016/0014-3057(92)90057-9
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
Polymers obtained from photosensitive copolymerizable systems show outstanding reactivity and durability. Excited state properties of photoinitiators containing unsaturated ethylenic groups have been studied by nanosecond time-resolved laser-spectroscopy, with respect to triplet state lifetimes, rate constants of interaction with the environment (oxygen, amines, monomers). Measurements of rates of polymerization (R(p)) in solution (at various monomer concentrations [M]) allowed comparison of the theoretical dependence of R(p) on [M] with the experimental results. Correlations are established and discussed.
引用
收藏
页码：1063 / 1067
页数：5
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