LOW-TEMPERATURE PREPARATION OF AMORPHOUS NIOBIUM SULFIDE

被引：12
|
作者：
BENSALEM, A
SCHLEICH, DM
机构：
[1] Polytechnic University, Brooklyn, NY 11201
来源：
MATERIALS RESEARCH BULLETIN | 1990年 / 25卷 / 03期
基金：
美国国家科学基金会;
关键词：
D O I：
10.1016/0025-5408(90)90107-D
中图分类号：
T [工业技术];
学科分类号：
08 ;
摘要：
A detailed study has been performed on the reactivity of niobium pentachloride with three different organic sulfurizing agents (CH3)3SiSSi(CH3)3, (CH3)3CSSC(CH3)3 and (CH3)3CSC(CH3)3. The nature of the organic agent does not seem to affect the Nb:S ratio in the obtained amorphous powder. However the purity of this powder is highly dependent on the organic sulfurizing agent and also the solvent. The obtained amorphous powder in all cases has a Nb/S ratio of 2.5, is highly reactive and converts rapidly to a crystalline niobium sulfide by simply heating at high temperature. © 1990.
引用
收藏
页码：349 / 356
页数：8
相关论文
共 50 条
  • [21] LOW-TEMPERATURE THERMAL PROPERTIES OF CADMIUM SULFIDE
    JIRMANUS, NS
    MCCARTHY, KA
    JOURNAL OF THE OPTICAL SOCIETY OF AMERICA, 1971, 61 (05) : 683 - &
  • [22] LOW-TEMPERATURE FORMATION FOR NICKEL-SULFIDE
    BLOCK, MR
    MULLER, O
    NAGEL, K
    METEORITICS, 1979, 14 (04): : 353 - 355
  • [23] GOLD DEPOSITION AT LOW-TEMPERATURE ON SULFIDE MINERALS
    BANCROFT, GM
    JEAN, G
    NATURE, 1982, 298 (5876) : 730 - 731
  • [24] DISLOCATION MECHANISM OF LOW-TEMPERATURE ACOUSTIC RELAXATION IN NIOBIUM
    PALVAL, PP
    NATSIK, VD
    PALVAL, LN
    FIZIKA NIZKIKH TEMPERATUR, 1995, 21 (06): : 647 - 662
  • [25] DISLOCATION-STRUCTURES IN DEFORMED NIOBIUM AT LOW-TEMPERATURE
    LOUCHET, F
    KUBIN, L
    JOURNAL DE MICROSCOPIE, 1974, 20 (01): : A10 - A10
  • [26] LOW-TEMPERATURE ELASTIC RESPONSE OF NIOBIUM CONTAINING HYDROGEN
    POKER, DB
    SETSER, GG
    GRANATO, AV
    BIRNBAUM, HK
    BULLETIN OF THE AMERICAN PHYSICAL SOCIETY, 1978, 23 (03): : 256 - 256
  • [27] LOW-TEMPERATURE ULTRASONIC STUDY OF TRAPPED HYDROGEN IN NIOBIUM
    BELLESSA, G
    PHYSICAL REVIEW B, 1985, 32 (08): : 5481 - 5482
  • [28] LOW-TEMPERATURE ULTRASONIC STUDY OF TRAPPED HYDROGEN IN NIOBIUM
    POKER, DB
    SETSER, GG
    GRANATO, AV
    BIRNBAUM, HK
    PHYSICAL REVIEW B, 1984, 29 (02): : 622 - 629
  • [29] LOW-TEMPERATURE ANELASTIC BEHAVIOR OF NIOBIUM CONTAINING HYDROGEN
    POKER, DB
    SETSER, GG
    GRANATO, AV
    BIRNBAUM, HK
    ZEITSCHRIFT FUR PHYSIKALISCHE CHEMIE-WIESBADEN, 1979, 116 : 39 - 45
  • [30] EXAMINATION OF SURFACE EFFECTS ON LOW-TEMPERATURE DEFORMATION OF NIOBIUM
    NAGAKAWA, J
    MESHII, M
    PHILOSOPHICAL MAGAZINE A-PHYSICS OF CONDENSED MATTER STRUCTURE DEFECTS AND MECHANICAL PROPERTIES, 1982, 45 (06): : 983 - 1002
12345