A DISTORTED TRIGONAL BIPYRAMIDAL MANGANESE(II) COMPLEX OF THE SCHIFF-BASE LIGAND (L) DERIVED FROM 2,6-PYRIDINEDICARBOXALDEHYDE AND (1R,2S)-NOREPHEDRINE - THE X-RAY STRUCTURE OF MNBR2L

被引：2

作者：

NAKAJIMA, K ^{[1
]}

KOJIMA, M ^{[1
]}

机构：

[1] OKAYAMA UNIV, FAC SCI, DEPT CHEM, OKAYAMA 700, JAPAN

来源：

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN | 1993年 / 66卷 / 07期

关键词：

D O I：

10.1246/bcsj.66.2109

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The title complex was synthesized and the structure was determined by the X-ray method. The oxygen atoms of the (1R,2S)-norephedrine moieties do not co-ordinate to manganese and the coordination polyhedron is a distorted trigonal bipyramid. The steric interactions between the bound bromide ions and the methyl and phenyl groups of the (1R,2S)-norephedrine moieties are suggested to influence the structure of the complex.

引用

页码：2109 / 2111

页数：3

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