THIOLATE COMPLEXES OF OSMIUM(IV) - PREPARATION OF [OS(SR)4(PR'3)] (R = C6F5, C6F4H-4, C6H4F-4 OR PH, R' = PH R = C6F5 OR C6F4H-4, R'3 = ME2PH) AND [OSCL(SC6F5)2(SC6H4X-3)(PME2PH)] (X=F OR CF3) - CRYSTAL-STRUCTURES OF [OS(SC6F4H-4)4(PPH3)] AND [OSCL(SC6F5)2(SC6H4CF3-3)(PME2PH)]

被引：23

作者：

ARROYO, M ^{[1
]}

CHAMIZO, JA ^{[1
]}

HUGHES, DL ^{[1
]}

RICHARDS, RL ^{[1
]}

ROMAN, P ^{[1
]}

SOSA, P ^{[1
]}

TORRENS, H ^{[1
]}

机构：

[1] UNIV SUSSEX,AFRC,IPSR,NITROGEN FIXAT LAB,BRIGHTON BN1 9RQ,E SUSSEX,ENGLAND

来源：

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 1994年 / 13期

关键词：

D O I：

10.1039/dt9940001819

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The diamagnetic osmium(IV) complexes [Os(SR)4(PR'3)] (R = C6F5, C6F4H-4, C6H4F-4, or Ph, R' = Ph; R = C6F5 or C6F4H-4, R'3, = Me2Ph) and [OsCl(SC6F5)2(SC6H4X-3)(PMe2Ph)] (X = F or CF3) have been prepared. The complex [Os(SC6F4H-4)4(PPh3)] has an essentially trigonal-bipyramidal structure with an apical PPh3 group [Os-P 2.391 (5), Os-S(ap) 2.414(5), mean Os-S(eq), 2.207(7) angstrom]. The structure of [OsCl(SC6F5)2(SC6H4CF3-3)(PMe2Ph)] is a somewhat distorted triagonal bipyramid with apical Cl- and PMe2Ph groups [Os-Cl 2.420(2), Os-P 2.340(2), mean Os-SC6F5 2.206(2), Os-SC6H4CF3 2.187(2) angstrom]. The spectroscopic properties of these compounds are reported and the possibility of isomerism in solution is discussed.

引用

页码：1819 / 1824

页数：6

共 50 条

[21] Synthesis and Structures of Tris(3-fluorophenyl)antimony Dicarboxylates (3-FC6H4)3Sb[OC(O)R]2 (R = CH2C6H4F-3, C6H3F2-2,3, and C6F5)
Sharutin, V. V.
Sharutina, O. K.
Zherebtsov, D. A.
El'tsov, O. S.
RUSSIAN JOURNAL OF COORDINATION CHEMISTRY, 2022, 48 (04) : 218 - 223
[22] Synthesis and Structure of Triphenylbismuth Dicarboxylates Ph3Bi[OC(O)R]2 (R = CH2C6H4F-3, C6H3F2-2,3, C6HF4-2,3,4,5)
Sharutin, V. V.
Sharutina, O. K.
Koscheeva, L., V
RUSSIAN JOURNAL OF GENERAL CHEMISTRY, 2021, 91 (05) : 840 - 843
[23] Synthesis and Structure of Triphenylbismuth Dicarboxylates Ph3Bi[OC(O)R]2 (R = CH2C6H4F-3, C6H3F2-2,3, C6HF4-2,3,4,5)
V. V. Sharutin
O. K. Sharutina
L. V. Koscheeva
Russian Journal of General Chemistry, 2021, 91 : 840 - 843
[24] Reactivity of C6F5S-P(C6H5)2 with [M3(CO)12] (M = Fe, Ru, Os).: The X-ray crystal structures of [Fe2(μ-SC6F5)(μ-PPh2)(CO)6], [Ru4(μ3-SPPh2)2(μ-SC6F5)2(μ-PPh2)2(SC6F5)2(CO)6] and [Os3(η1-Ph2P-SC6F5)(CO)11]
Baldovino-Pantaleón, O
Ríos-Moreno, G
Toscano, RA
Morales-Morales, D
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2005, 690 (12) : 2880 - 2887
[25] Carbon-Fluorine Bond Activation in Thermolysis Reactions of the Osmium(IV) Perfluorothiolate Compounds [Os(SC6F5)4(P(C6H4X-4)3)] (X = CF3, Cl, F, H, CH3, and OCH3)
Mendoza, Consuelo
Bernes, Sylvain
Torrens, Hugo
Arroyo, Maribel
ORGANOMETALLICS, 2010, 29 (12) : 2646 - 2659
[26] Synthesis and reactivity of [N(C6H4Br)3][B(C6F5)4]:: the X-ray crystal structure of [Fe(C5H5)2][B(C6F5)4]
O'Connor, AR
Nataro, C
Golen, JA
Rheingold, AL
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2004, 689 (14) : 2411 - 2414
[27] Square [Pd4(μ-CN)4(C6F5)4(PEt3)4]•2C6H5CH3
Charmant, JPH
Espinet, P
Soulantica, K
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2001, 57 : m451 - m453
[28] Synthesis and reactivity of trinuclear gold(III) dithiolate complexes. X-ray structure of [Au(CR6F5)(S2C6H4)]3 and [Au(C6F5)(S2C6H4)(SC6H4SPPh3) ]
Cerrada, Elena
Fernandez, Eduardro J.
Jones, Peter G.
Laguna, Antonio
Laguna, Mariano
Terroba, Raquel
Organometallics, 1995, 14 (12):
[29] Synthesis and structure of ruthenium complexes [Ph3PCH2C6H4F-4]2[RuCl6] and [Ph3PCH2C6H4F-4][trans-RuCl4(dmso-S)2]
V. V. Sharutin
O. K. Sharutina
V. S. Senchurin
M. I. Kodess
Russian Chemical Bulletin, 2017, 66 : 946 - 950
[30] Synthesis and structure of ruthenium complexes [Ph3PCH2C6H4F-4]2[RuCl6] and [Ph3PCH2C6H4F-4][trans-RuCl4(dmso-S)2]
Sharutin, V. V.
Sharutina, O. K.
Senchurin, V. S.
Kodess, M. I.
RUSSIAN CHEMICAL BULLETIN, 2017, 66 (06) : 946 - 950

← 1 2 3 4 5 →