SYNTHESIS OF 2-(SUBSTITUTED METHYL)-3,4-DISUBSTITUTED PYRROLES AND THEIR CONVERSION INTO THE CORRESPONDING PORPHYRINS

被引：10

作者：

KINOSHITA, H ^{[1
]}

TANAKA, S ^{[1
]}

NISHIMORI, N ^{[1
]}

DEJIMA, H ^{[1
]}

INOMATA, K ^{[1
]}

机构：

[1] KANAZAWA UNIV, FAC SCI, DEPT CHEM, MARUNOUCHI 1-1, KANAZAWA, ISHIKAWA 920, JAPAN

来源：

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN | 1992年 / 65卷 / 10期

关键词：

D O I：

10.1246/bcsj.65.2660

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

2-Hydroxymethyl-1-methylsulfonyl-3,4-disubstituted pyrroles and 2-hydroxymethyl-3,4-disubstituted pyrroles were effectively converted into the corresponding 2-(substituted methyl)pyrrole derivatives by the reaction with various nucleophiles in the presence of base. These products were further transformed to the corresponding porphyrins regioselectively under almost neutral or basic conditions.

引用

页码：2660 / 2667

页数：8

共 50 条

[41] Synthesis of some new 3,4-disubstituted pyrroles and pyrazoles from E-1-(arylsulfonylethylsulfonyl)-2-arylethene
Padmaja, A.
Syamaiah, K.
Muralikrishna, A.
Padmavathi, V.
INDIAN JOURNAL OF CHEMISTRY SECTION B-ORGANIC CHEMISTRY INCLUDING MEDICINAL CHEMISTRY, 2012, 51 (01): : 285 - 290
[42] Stereoselective Synthesis of 3-Substituted and 3,4-Disubstituted Piperidine und Piperidin-2-one Derivatives
Klegraf, Ellen
Kunz, Horst
ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 2012, 67 (04): : 389 - 405
[43] ASYMMETRIC NITROALKENE [4+2] CYCLOADDITIONS - ENANTIOSELECTIVE SYNTHESIS OF 3-SUBSTITUTED AND 3,4-DISUBSTITUTED PYRROLIDINES
DENMARK, SE
MARCIN, LR
JOURNAL OF ORGANIC CHEMISTRY, 1995, 60 (10): : 3221 - 3235
[44] Selective synthesis of unsymmetrical 3,4-disubstituted and 4-substituted 2(5H)-furanones
Rossi, R
Bellina, F
Raugei, E
SYNLETT, 2000, (12) : 1749 - 1752
[45] THE CONDUCTING POLY(3,4-DISUBSTITUTED PYRROLES) DOPED WITH ORGANIC ELECTRON-ACCEPTORS
KANEKO, T
MATSUI, N
KAMIYAMA, M
YAGIHARA, T
SYNTHETIC METALS, 1993, 55 (2-3) : 1091 - 1095
[46] A new synthesis of 3,4-disubstituted 1,2,5-thiadiazoles
Biju, Purakkattle
Yu, Younong
TETRAHEDRON LETTERS, 2007, 48 (30) : 5279 - 5282
[47] USE OF 2,5-DICHLOROTHIOPHENE IN SYNTHESIS OF 3,4-DISUBSTITUTED THIOPHENES
MACDOWELL, DW
PATRICK, TB
FRAME, BK
ELLISON, DL
JOURNAL OF ORGANIC CHEMISTRY, 1967, 32 (04): : 1226 - +
[48] SYNTHESIS AND ABSORPTION SPECTRA OF 3,4-DISUBSTITUTED DIBENZOSELENOPHENE DERIVATIVES
SAWICKI, E
JOURNAL OF ORGANIC CHEMISTRY, 1954, 19 (07): : 1163 - 1170
[49] Synthesis of 2,4-Disubstituted Pyrroles by Rearrangements of 2-Furanyl Carbamates
Kiren, Sezgin
Hong, Xuechuan
Leverett, Carolyn A.
Padwa, Albert
ORGANIC LETTERS, 2009, 11 (06) : 1233 - 1235
[50] Synthesis of 3,4-disubstituted 4-aminobutanoic acids
O. S. Vasil’eva
E. S. Ostroglyadov
A. A. Nikonorov
O. V. Komarova
V. M. Berestovitskaya
Russian Journal of Organic Chemistry, 2016, 52 : 904 - 905

← 1 2 3 4 5 →