SILAFUNCTIONAL COMPOUNDS IN ORGANIC-SYNTHESIS .48. ORTHO-LITHIATION DIRECTED BY AMINO-GROUPS ON SILICON IN PHENYLSILANE DERIVATIVES

被引：20

作者：

TAMAO, K

YAO, H

TSUTSUMI, Y

ABE, H

HAYASHI, T

ITO, Y

机构：

[1] Department of Synthetic Chemistry, Faculty of Engineering, Kyoto University, Kyoto

来源：

TETRAHEDRON LETTERS | 1990年 / 31卷 / 20期

关键词：

D O I：

10.1016/0040-4039(90)80186-P

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Phenylsilanes, which contain trimethylethylenediamino (Me2NCH2CH2NMe-) group(s) on silicon, undergo selective ortho lithiation by treatment with t-BuLi, providing a new method for the synthesis of ortho substituted phenylsilane derivatives. © 1990.

引用

页码：2925 / 2928

页数：4

共 24 条

[21] STUDIES ON ORGANIC FLUORINE-COMPOUNDS .48. SYNTHESIS OF FLUORO-OLEFINS BY THE RING-OPENING REACTION OF GEM-DIFLUOROCYCLOPROPANE DERIVATIVES
TAGUCHI, T
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NIPPON KAGAKU KAISHI, 1985, (11) : 2177 - 2184
[22] SILAFUNCTIONAL COMPOUNDS IN ORGANIC-SYNTHESIS .46. PLATINUM-CATALYZED INTRAMOLECULAR HYDROSILATION OF ALLYLAMINES - FORMATION OF 1-AZA-2-SILACYCLOBUTANES AND APPLICATION TO STEREOSELECTIVE SYNTHESIS OF 2-AMINO ALCOHOLS
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[23] STUDIES OF THE USE OF ELEMENTO-ORGANIC COMPOUNDS OF THE 15TH AND 16TH GROUPS IN ORGANIC-SYNTHESIS .71. REACTION OF ALPHA-HALOGENO CARBOXYLIC DERIVATIVES WITH CARBONYL-COMPOUNDS PROMOTED BY TRIBUTYLSTIBINE
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[24] ORGANOFLUOROSILICATES IN ORGANIC-SYNTHESIS .15. REACTION OF EXO-5-NORBORNEN-2-YLSILYL AND ENDO-5-NORBORNEN-2-YLSILYL DERIVATIVES WITH N-BROMOSUCCINIMIDE - DIFFERENCE IN REACTIVITY BETWEEN HEXACOORDINATE AND TETRACOORDINATE SILICON-COMPOUNDS
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