SILAFUNCTIONAL COMPOUNDS IN ORGANIC-SYNTHESIS .48. ORTHO-LITHIATION DIRECTED BY AMINO-GROUPS ON SILICON IN PHENYLSILANE DERIVATIVES

被引：20
|
作者：
TAMAO, K
YAO, H
TSUTSUMI, Y
ABE, H
HAYASHI, T
ITO, Y
机构：
[1] Department of Synthetic Chemistry, Faculty of Engineering, Kyoto University, Kyoto
来源：
TETRAHEDRON LETTERS | 1990年 / 31卷 / 20期
关键词：
D O I：
10.1016/0040-4039(90)80186-P
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Phenylsilanes, which contain trimethylethylenediamino (Me2NCH2CH2NMe-) group(s) on silicon, undergo selective ortho lithiation by treatment with t-BuLi, providing a new method for the synthesis of ortho substituted phenylsilane derivatives. © 1990.
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页码：2925 / 2928
页数：4
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