REACTION OF PENTAFLUORONITROSOBENZENE WITH [OS3H(MU-H)(CO)10(MPH3)] (M=P, AS, SB) - SYNTHESIS AND X-RAY STRUCTURE OF [OS3(MU-H)(CO)10(PPH3)(ONC6F4O)]

被引：3

作者：

ANG, HG

KWIK, WL

ONG, KK

机构：

[1] Department of Chemistry, National University of Singapore, Singapore, 0511, Lower Kent Ridge Road

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1994年 / 474卷 / 1-2期

关键词：

OSMIUM; SYNTHESIS;

D O I：

10.1016/0022-328X(94)84059-8

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The pentafluoronitrosobenzene C6F5NO has been shown from infrared spectral, F-19 NMR spectral and single-crystal X-ray diffraction studies to undergo oxidation at the para-position upon reaction with [Os3H(mu-H)(CO)10(PPh3)] to afford [Os3(mu-H)(CO)10(PPh3)(ONC6F4O)](I). The arsenic- and stibine- analogues of I ([Os3(mu-H)(CO)10(MPh3)(ONC6F4O)) (M = As, Sb)) were also isolated.

引用

页码：149 / 152

页数：4

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