ADSORPTION OF SURFACTANTS ON SOLUTION AIR AND SOLUTION MEMBRANE INTERFACES

被引：0
|
作者：
PLAKATINA, TP
KIM, V
KOCHERGIN, NV
机构：
来源：
COLLOID JOURNAL OF THE RUSSIAN ACADEMY OF SCIENCES | 1993年 / 55卷 / 06期
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中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Methods of precision tensiometry and two-phase titration were used to determine thermodynamic parameters of the Gibbs adsorption of ionogenic surfactants at solution/air and solution/cellulose acetate membrane interfaces. It was shown that the adsorption equilibrium constant and the limiting monolayer capacity of the surfactants studied depend significantly on the ionic strength and pH of the solution. The role of electrostatic and specific effects on the adsorption capacity of ionic surfactants is examined.
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页码：855 / 859
页数：5
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