SYNTHESIS OF SPIRO GAMMA-LACTONES FROM CONJUGATED DIENES

被引：13

作者：

XIONG, HP ^{[1
]}

RIEKE, RD ^{[1
]}

机构：

[1] UNIV NEBRASKA,DEPT CHEM,LINCOLN,NE 68588

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1992年 / 57卷 / 26期

关键词：

D O I：

10.1021/jo00052a004

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Stepwise reactions of conjugated dienemagnesium reagents with a ketone at -78-degrees-C, followed by carbon dioxide at 0-degrees-C to room temperature, provide a one-pot method for the synthesis of spiro gamma-lactones containing a vinyl group at the beta-position.

引用

页码：7007 / 7008

页数：2

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