POLYMER-BOUND PALLADIUM ACETATE AS A CATALYST FOR THE REDUCTION OF NITRO AND AZO GROUPS

被引：11

作者：

MANI, R ^{[1
]}

MAHADEVAN, V ^{[1
]}

SRINIVASAN, M ^{[1
]}

机构：

[1] INDIAN INST TECHNOL,DEPT CHEM,MADRAS 600036,TAMIL NADU,INDIA

来源：

REACTIVE POLYMERS | 1991年 / 14卷 / 03期

关键词：

D O I：

10.1016/0923-1137(91)90042-M

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

Palladium acetate anchored to a copolymer containing pyridyl and carboxyl groups has been employed as a catalyst for the hydrogenation of azo and nitro groups under 1 atm hydrogen pressure and 30-degrees-C. The selective hydrogenation of azobenzene using a polymer-bound palladium catalyst is reported for the first time. Kinetic data on the hydrogenation of azo-benzene are also presented.

引用

页码：263 / 268

页数：6

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