POLYMER-BOUND PALLADIUM ACETATE AS A CATALYST FOR THE REDUCTION OF NITRO AND AZO GROUPS

被引：11
|
作者：
MANI, R [1 ]
MAHADEVAN, V [1 ]
SRINIVASAN, M [1 ]
机构：
[1] INDIAN INST TECHNOL,DEPT CHEM,MADRAS 600036,TAMIL NADU,INDIA
来源：
REACTIVE POLYMERS | 1991年 / 14卷 / 03期
关键词：
D O I：
10.1016/0923-1137(91)90042-M
中图分类号：
O69 [应用化学];
学科分类号：
081704 ;
摘要：
Palladium acetate anchored to a copolymer containing pyridyl and carboxyl groups has been employed as a catalyst for the hydrogenation of azo and nitro groups under 1 atm hydrogen pressure and 30-degrees-C. The selective hydrogenation of azobenzene using a polymer-bound palladium catalyst is reported for the first time. Kinetic data on the hydrogenation of azo-benzene are also presented.
引用
收藏
页码：263 / 268
页数：6
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