The crystal structures of tetrakis(mu-n-butyrat-kappa O-2:O ')bis[bromidorhenium(III)] and tetrakis(mu-n-butyrato-kappa O-2:O ')bis[chloridorhenium(III)] acetonitrile disolvate

被引：0
|
作者：
Reed, Carly R. [1 ]
Brennessel, William W. [2 ]
机构：
[1] SUNY Coll Brockport, Dept Chem & Biochem, Brockport, NY 14420 USA
[2] Univ Rochester, Dept Chem, Rochester, NY 14627 USA
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2015年 / 71卷
关键词：
crystal structure; dihalidoetrakis(-butyrato)dirhenium(III; III); dirheniurn tetracarboxylate; quadruple bond; paddlewheel complex;
D O I：
10.1107/S2056989015020563
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
The title complexes, [Re2Br2(O2CC3H7)(4)], (1), and [Re-2(O2CC3H7)(4)Cl-2]center dot 2CH(3)CN, (2), both exhibit paddlewheel structures with four carboxylate ligands bridging two Re-III atoms. The Re-Re distances are 2.2325 (2) and 2.2299 (3) angstrom, indicating quadruple bonds between the Re-III atoms in each complex. Both complexes contain an inversion center at the mid-point of the Re-Re bond. The Re-Br bond [2.6712 (3) angstrom] in (1) is 0.1656 (6) angstrom longer than the Re-Cl distance [2.5056 (5) angstrom] of (2). In (2), the N atom of each co-crystallized acetonitrile solvent molecule is nearly equidistant between and in close contact with two carboxylate C atoms.
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收藏
页码：1480 / +
页数：12
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