Methyl 3,5-bis(cyclohexylmethoxy)-benzoate

被引：2
|
作者：
Corfield, Peter W. R. [1 ]
Paccagnini, Michele L. [1 ]
Balija, Amy M. [1 ]
机构：
[1] Fordham Univ, Dept Chem, 441 East Fordham Rd, Bronx, NY 10458 USA
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2014年 / 70卷
关键词：
D O I：
10.1107/S1600536814004607
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
In the title compound, C22H32O4, the atoms of the methyl ester group and the alkoxy O atoms are all coplanar with the central aromatic ring, with an r.m.s. deviation of 0.008 angstrom. Bonds to the methylene and cyclohexyl groups are also very close to this plane, so that the molecule is essentially flat, apart from the cyclohexyl groups. The mean planes through the cyclohexyl groups are tilted by 30.08 (9) and 36.14 (7)degrees with respect to the central aromatic ring. In the crystal, pairs of molecules linked by C-H center dot center dot center dot O hydrogen bonds form planar units which are stacked along the a axis, with an average interplanar distance of 3.549 (2) angstrom. Stacking appears to be stabilized by further weak C-H center dot center dot center dot O hydrogen bonds.
引用
收藏
页码：O400 / +
页数：12
相关论文
共 50 条
  • [21] 3,5-Bis[4-(diethylamino)benzylidene]-1-methyl-4-piperidone and 3,5-bis[4-(diethylamino)cinnamylidene]-1-methyl-4-piperidone: prospective biophotonic materials
    Nesterov, VN
    Timofeeva, TV
    Sarkisov, SS
    Leyderman, A
    Charles, CYC
    Antipin, MY
    ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY, 2003, 59 (11): : O605 - O608
  • [22] An improved preparation of 3,5-bis(trifluoromethyl)acetophenone and safety considerations in the preparation of 3,5-bis(trifluoromethyl)phenyl Grignard reagent
    Leazer, JL
    Cvetovich, R
    Tsay, FR
    Dolling, U
    Vickery, T
    Bachert, D
    JOURNAL OF ORGANIC CHEMISTRY, 2003, 68 (09): : 3695 - 3698
  • [23] A MANGANESE(III) COMPLEX OF 3,5-BIS((SALICYLIDENEAMINO)METHYL)PYRAZOLE - SYNTHESIS, STRUCTURE, AND PROPERTIES
    SHINDO, K
    MORI, Y
    MOTODA, K
    SAKIYAMA, H
    MATSUMOTO, N
    OKAWA, H
    INORGANIC CHEMISTRY, 1992, 31 (24) : 4987 - 4990
  • [24] Synthesis of 1-Methyl and 1-Benzyl 3,5-Bis(ω-Mercaptoalkyl) Isocyanurates
    S. G. Fattakhov
    M. M. Shulaeva
    V. S. Reznik
    Russian Journal of General Chemistry, 2001, 71 : 956 - 959
  • [25] Synthesis of 1-methyl and 1-benzyl 3,5-bis(ω-mercaptoalkyl) isocyanurates
    Fattakhov, SG
    Shulaeva, MM
    Reznik, VS
    RUSSIAN JOURNAL OF GENERAL CHEMISTRY, 2001, 71 (06) : 956 - 959
  • [26] Crystal structures of methyl 3,5-dibromo-4-cyano-benzoate and methyl 3,5-dibromo-4-isocyano-benzoate
    Noland, Wayland E.
    Herzig, Ryan J.
    Engwall, Abigail J.
    Jensen, Renee C.
    Tritch, Kenneth J.
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2018, 74 : 345 - +
  • [27] 3,5-Bis(4-fluorophenyl)isoxazole
    Fun, Hoong-Kun
    Arshad, Suhana
    Samshuddin, S.
    Narayana, B.
    Sarojini, B. K.
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2012, 68 : O1783 - +
  • [28] 3,5-Bis(benzothiazolyl)-Substituted BODIPY Dyes
    Poronik, Yevgen M.
    Yakubovskyi, Viktor P.
    Shandura, Mykola P.
    Vlasenko, Yuriy G.
    Chernega, Alexander N.
    Kovtun, Yuriy P.
    EUROPEAN JOURNAL OF ORGANIC CHEMISTRY, 2010, 2010 (14) : 2746 - 2752
  • [29] [3,5-Bis(trifluoromethyl)phenyl]{(E)-2-[(E)-3,5-bis(trifluoromethyl)phenylimino]-1-methylpropylidene}amine
    Aberdeen, HL
    Allen, RE
    Crane, JD
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2003, 59 : O1896 - O1897
  • [30] Synthesis of 3,5-Bis(hydroxymethyl)adamantan-1-ols and 3,5-Bis(nitrooxymethyl)adamantan-1-yl Nitrates
    Ivleva, E. A.
    Kazakova, A. I.
    Klimochkin, Yu. N.
    RUSSIAN JOURNAL OF ORGANIC CHEMISTRY, 2020, 56 (09) : 1562 - 1569
12345