catena-Poly[[[(1,10-phenanthroline-kappa N-2,N') praseodymium(III)]-di-mu-4-hydroxybenzoato-kappa O-4(1):O-1'-mu-nitrato-kappa O-3,O':O] bis(1,10-phenanthroline)]

被引：1
|
作者：
Wang, Panfeng [1 ]
Xu, Dingding [1 ]
Wang, Xinqing [1 ]
机构：
[1] China Jiliang Univ, Coll Mat Sci & Engn, Hangzhou 310018, Zhejiang, Peoples R China
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2012年 / 68卷
关键词：
D O I：
10.1107/S1600536812029911
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
The title complex, [Pr(C7H5O3)(2)(NO3)(C12H8N2)]center dot 2C(12)H(8)N(2), has a polymeric chain structure, with two uncoordinated 1,10-phenanthroline molecules in the lattice. The Pr III centre has a monocapped square-antiprismatic coordination geometry, comprised of two N atoms from one chelating 1,10-phenanthroline ligand, four carboxylate O atoms from four 4-hydroxybenzoate anions and three O atoms from two nitrate anions. The 4-hydroxybenzoate and nitrate anions function as mu(2)-bridging ligands and link the Pr-III ions into a onedimensional chain structure along the c axis. Intermolecular O-H center dot center dot center dot N hydrogen bonds are observed between the 4-hydroxybenzoate anions and the uncoordinated 1,10-phenanthroline molecules.
引用
收藏
页码：M1148 / +
页数：13
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