STRUCTURE AND BONDING IN [TACL4(C5H5N)2]

被引：12
|
作者：
MILLER, GJ [1 ]
LIN, JH [1 ]
YOUNG, V [1 ]
机构：
[1] IOWA STATE UNIV SCI & TECHNOL,DEPT CHEM,AMES,IA 50011
来源：
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 1993年 / 49卷
关键词：
D O I：
10.1107/S0108270193003919
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The title structure, tetrachlorobis(pyridine)tantalum, is characterized by monomeric octahedral complexes, TaCl4(py)2 (py is pyridine), with the pyridine ligands coordinated in a trans configuration. In addition to packing (steric) arguments, an electronic driving force for the observed structure is incorporated, which is evaluated using extended Huckel calculations.
引用
收藏
页码：1770 / 1773
页数：4
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