TRIPLET ELECTRONIC STATES OF THE ETHENE DICATION

被引:5
|
作者
GRIFFITHS, WJ [1 ]
HARRIS, FM [1 ]
机构
[1] UNIV COLL SWANSEA,MASS SPECTROMETRY RES UNIT,SINGLETON PK,SWANSEA SA2 8PP,W GLAM,WALES
关键词
DOUBLE-CHARGE-TRANSFER; ETHENE DICATION; DOUBLE-IONIZATION ENERGIES;
D O I
10.1016/0168-1176(92)87022-7
中图分类号
O64 [物理化学(理论化学)、化学物理学]; O56 [分子物理学、原子物理学];
学科分类号
070203 ; 070304 ; 081704 ; 1406 ;
摘要
Double-charge-transfer spectroscopy has been used to measure double-ionization energies to various electronic states of the ethene dication. Because OH+ was used as the projectile ion, it is likely, on the evidence of the results from numerous similar studies of other molecules, that triplet dication states were populated. Although the density of C2H42+ states is high, it is shown that suitable groupings of calculated triplet-state energies agree well with the energies measured.
引用
收藏
页码:321 / 329
页数:9
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