The Synthesis and Physico-chemical Studies of Complexes Trans-Dichloro-bis-(amin)platinum(II)

被引:0
|
作者
Starkov, Alexander K. [1 ]
Kozuchovskaya, Galina A. [1 ]
机构
[1] Russian Acad Sci, Siberian Branch, Inst Chem & Chem Technol, 42 K Marx St, Krasnoyarsk 660049, Russia
来源
JOURNAL OF SIBERIAN FEDERAL UNIVERSITY-CHEMISTRY | 2011年 / 4卷 / 04期
关键词
complex compounds of platinum; synthesis; physicochemical properties; amines;
D O I
暂无
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The new methods of synthesis and some physico-chemical properties of trans-dichlorobis-(amin)platinum(II) complexes with the formula trans-[PtA2Cl2], where A - methylamine, ethylamine, and isopropylamine were described. These methods allow to increase the yield and purity of substances. Their solubilites were studied at a temperature of 20 degrees C in a solution of 0.5 M KCl. To prove the identity, structure and characterization of physico-chemical properties of the complexes the methods of elemental analysis, XRD, IR, thermogravimetric analysis, UV-spectrophotometry were used.
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页码:377 / 383
页数:7
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