The Synthesis and Physico-chemical Studies of Complexes Trans-Dichloro-bis-(amin)platinum(II)

被引:0
|
作者
Starkov, Alexander K. [1 ]
Kozuchovskaya, Galina A. [1 ]
机构
[1] Russian Acad Sci, Siberian Branch, Inst Chem & Chem Technol, 42 K Marx St, Krasnoyarsk 660049, Russia
来源
关键词
complex compounds of platinum; synthesis; physicochemical properties; amines;
D O I
暂无
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The new methods of synthesis and some physico-chemical properties of trans-dichlorobis-(amin)platinum(II) complexes with the formula trans-[PtA2Cl2], where A - methylamine, ethylamine, and isopropylamine were described. These methods allow to increase the yield and purity of substances. Their solubilites were studied at a temperature of 20 degrees C in a solution of 0.5 M KCl. To prove the identity, structure and characterization of physico-chemical properties of the complexes the methods of elemental analysis, XRD, IR, thermogravimetric analysis, UV-spectrophotometry were used.
引用
收藏
页码:377 / 383
页数:7
相关论文
共 50 条
  • [1] The Synthesis and Physico-Chemical Studies of Nonsymmetric Complexes Trans-Dichlorodiaminplatinum(II)
    Starkov, Alexander K.
    Kozuchovskaya, Galina A.
    JOURNAL OF SIBERIAN FEDERAL UNIVERSITY-CHEMISTRY, 2013, 6 (02): : 203 - 209
  • [2] trans-Dichloro-bis-(arylazoimidazole)palladium(II): Synthesis, Structure, Photoisomerization, and DFT Calculation
    Pratihar, P.
    Mondal, T. K.
    Patra, A. K.
    Sinha, C.
    INORGANIC CHEMISTRY, 2009, 48 (07) : 2760 - 2769
  • [3] Synthesis and physico-chemical studies on cobalt(II), nickel(II) and copper(II) complexes of benzidine diacetyloxime
    El-Tabl, AS
    TRANSITION METAL CHEMISTRY, 2002, 27 (02) : 166 - 170
  • [4] Synthesis, crystal structure and intermolecular contacts in trans-bis(ethylamine) dichloro platinum(II) and palladium(II) complexes
    Mulagaleev, Ruslan F.
    Starkov, Aleksandr K.
    Zaitseva, Yulia N.
    Kozhuhovskay, Galina A.
    Pavlenko, Nina, I
    Kirik, Sergei D.
    JOURNAL OF MOLECULAR STRUCTURE, 2020, 1199
  • [5] Synthesis and physico-chemical studies on cobalt(II), nickel(II) and copper(II) complexes of benzidine diacetyloxime
    Abdou Saad El-Tabl
    Transition Metal Chemistry, 2002, 27 : 166 - 170
  • [6] Synthesis, structure and physico-chemical studies of Mn (II) complexes of salicylaldehyde derived semicarbazone and thiosemicarbazone
    Sharma, Navin Kumar
    Sapna
    Agarwal, Manoj
    Kohli, Seema
    Tiwari, B.
    Gurtu, J. N.
    Agarwal, Bhavna
    ORIENTAL JOURNAL OF CHEMISTRY, 2010, 26 (01) : 103 - 108
  • [7] Physico-chemical studies on Cu(II) complexes of acrylate chelating polymers
    Senna, MM
    Siyam, T
    Mahdy, S
    JOURNAL OF MACROMOLECULAR SCIENCE-PURE AND APPLIED CHEMISTRY, 2004, A41 (10): : 1187 - 1203
  • [8] Synthesis, reactivity and physico-chemical studies of some novel mixed ligand complexes of copper(II)
    Dubey, RK
    Mishra, CM
    Mishra, AN
    INDIAN JOURNAL OF CHEMISTRY SECTION A-INORGANIC BIO-INORGANIC PHYSICAL THEORETICAL & ANALYTICAL CHEMISTRY, 2005, 44 (06): : 1159 - 1164
  • [9] Synthesis and physico-chemical studies of Pd(II) complexes derived from heterocyclic Schiff bases
    Sampat, NM
    Mehta, BH
    ASIAN JOURNAL OF CHEMISTRY, 1996, 8 (02) : 261 - 264
  • [10] Synthesis and physico-chemical studies of cyclometalated heteroleptic iridium(III) complexes
    Jayabharathi, Jayaraman
    Thanikachalam, Venugopal
    Srinivasan, Natesan
    Jayamoorthy, Karunamoorthy
    SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY, 2012, 93 : 240 - 244