STANDARD ENTHALPIES OF FE(III), RU(III) ACETYLACETONATES AND METAL OXYGEN BOND-ENERGIES FORMATION

被引：0

作者：

GERASIMOV, PA ^{[1
]}

GERASIMOVA, AI ^{[1
]}

MOROZOVA, NB ^{[1
]}

IGUMENOV, IK ^{[1
]}

机构：

[1] RUSSIAN ACAD SCI,SIBERIAN DIV,INST INORGAN CHEM,NOVOSIBIRSK,RUSSIA

来源：

SIBIRSKII KHIMICHESKII ZHURNAL | 1993年 / 01期

关键词：

D O I：

暂无

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Standard enthalpies of Fe(III) and Ru(III) acetylacetonates formation (-DELTA(f)H-degrees, kJ . mole-1) were determined by bomb oxygen combustion calorimetry: 1314,6 +/- 12,4 and 1054,5 +/- 8,8 respectively. The enthalpies of sublimation (DELTA(sub)H) of the complexes: 114,2 +/- 1,5 kJ . mole-1 (338-355 K) and 101,5 +/- 1,0 kJ . mole-1 (358-378 K) were determined with the help of a high vacuum device by Langmure technique. Metal-oxygen bond energies were calvulated: E(Fe-O) = 131 +/- 4 kJ . mole-1 and E(Ru-O) = = 130 +/- 4 kJ . mole-1 (at DELTAH(R)(RO-H) = 326 +/- 5 kJ . mole-1).

引用

页码：87 / 91

页数：5

共 50 条

[31] STANDARD ENTHALPIES OF FORMATION OF DIPHENYL OXALATE AND BENZOIC ANHYDRIDE AND SOME RELATED BOND DISSOCIATION ENERGIES
CARSON, AS
FINE, DH
GRAY, P
LAYE, PG
JOURNAL OF THE CHEMICAL SOCIETY B-PHYSICAL ORGANIC, 1971, (08): : 1611 - &
[32] HOMOLYSIS AND ACIDOLYSIS REACTIONS OF (ALPHA-HYDROXYALKYL)-CHROMIUM(III) AND (ALPHA-ALKOXYALKYL)CHROMIUM(III) COMPLEXES - KINETICS, STERIC EFFECTS, AND BOND-ENERGIES
KIRKER, GW
BAKAC, A
ESPENSON, JH
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1982, 104 (05) : 1249 - 1255
[33] Effect of Cr(III), Fe(III), Co(III), and Ni(II) acetylacetonates on the formation and thermal oxidative degradation of epoxy-anhydride polymers and composites
A. A. Lugovaya
V. M. Mikhal’chuk
V. A. Beloshenko
D. V. Gurtovoi
Russian Journal of Applied Chemistry, 2008, 81 : 2002 - 2007
[34] Effect of Cr(III), Fe(III), Co(III), and Ni(II) acetylacetonates on the formation and thermal oxidative degradation of epoxy-anhydride polymers and composites
Lugovaya, A. A.
Mikhal'chuk, V. M.
Beloshenko, V. A.
Gurtovoi, D. V.
RUSSIAN JOURNAL OF APPLIED CHEMISTRY, 2008, 81 (11) : 2002 - 2007
[35] METAL-CARBON BOND-DISSOCIATION ENERGIES AND ENTHALPIES OF FORMATION FOR GASEOUS METAL-CARBONYLS
BEHRENS, RG
JOURNAL OF THE LESS-COMMON METALS, 1978, 58 (01): : 47 - 54
[36] Effect of Cr(III), Fe(III), Co(III), and Ni(II) acetylacetonates on the formation and thermal oxidative degradation of epoxy-anhydride polymers and composites
Donetsk National University, Donetsk, Ukraine
不详
Russian Journal of Applied Chemistry, 2008, 81 (11): : 2002 - 2007
[37] METAL METAL BOND FORMATION IN THE CHEMISTRY OF ZR(III) - A CHEMICAL APPROACH
GAMBAROTTA, S
CHIANG, MY
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1988, 195 : 86 - INOR
[38] Standard enthalpies of formation and metal-ligand bond dissociation enthalpies of some lead(II) QQ -diketonates
Thermochim Acta, 2 (107):
[39] Metal-Assisted oxygen addition to an Fe(III)-thiolate
Blakely, Maike
Villar-Acevedo, Gloria
Dedushko, Maksym
Kaminsky, Werner
Kovacs, Julie
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2017, 253
[40] Vapour pressures and standard molar enthalpies of sublimation of two crystalline iron(III) beta-diketonates. The mean molar (Fe-O) bond-dissociation enthalpies
daSilva, MAVR
Monte, MJS
Huinink, J
JOURNAL OF CHEMICAL THERMODYNAMICS, 1996, 28 (04): : 413 - 419

← 1 2 3 4 5 →