RADICAL POLYMERIZATION OF 2-METHYLENE-1, 3-DITHIANE

被引：5
|
作者：
KOBAYASHI, S
KADOKAWA, J
SHODA, S
UYAMA, H
机构：
[1] Department of Molecular Chemistry and Engineering, Faculty of Engineering, Tohoku University, Aoba
来源：
JOURNAL OF MACROMOLECULAR SCIENCE-CHEMISTRY | 1991年 / A28卷
关键词：
D O I：
10.1080/00222339108054376
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
Radical polymerization of 2-methylene-1,3-dithiane, a six-membered cyclic dithioacetal, was carried out to give polymer possessing mainly dithioacetal unit by vinylidene polymerization without ring-opening. The structure was confirmed by H-1, C-13, IR, and UV spectroscopy. On the other hand, a seven-membered cyclic dithioacetal did not polymerize radically.
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页码：1 / 5
页数：5
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