A ONE-POT SYNTHESIS OF CYCLOPROPANES FROM AROMATIC-ALDEHYDES AND STYRENE VIA IRON CARBENE COMPLEXES

被引:2
|
作者
VARGAS, RM [1 ]
HOSSAIN, MM [1 ]
机构
[1] UNIV WISCONSIN,DEPT CHEM,MILWAUKEE,WI 53211
关键词
CATALYSIS; CYCLOPROPANATION; IRON COMPLEXES; CARBENE COMPLEXES;
D O I
10.1016/0020-1693(94)03981-X
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
A one-pot preparation of cyclopropanes from aromatic aldehydes and styrene via iron carbene complexes is reported. The preparation consisted of a sequence of reactions, involving initial addition of aldehyde to the Fp anion, followed by chlorotrimethylsilane and finally styrene in the presence of trimethylsilyltriflate.
引用
收藏
页码:159 / 160
页数:2
相关论文
共 50 条
  • [1] A ONE-POT ORTHO-ALKYLATION OF AROMATIC-ALDEHYDES
    COMINS, DL
    BROWN, JD
    MANTLO, NB
    TETRAHEDRON LETTERS, 1982, 23 (39) : 3979 - 3982
  • [2] Stereoselective one-pot synthesis of vinylsilanes from aromatic aldehydes
    Kwan, ML
    Yeung, CW
    Breno, KL
    Doxsee, KM
    TETRAHEDRON LETTERS, 2001, 42 (08) : 1411 - 1413
  • [3] One-pot synthesis of multifunctionalized cyclopropanes
    Chang, Meng-Yang
    Chen, Yi-Chia
    Chan, Chieh-Kai
    TETRAHEDRON, 2014, 70 (13) : 2257 - 2263
  • [4] ASYMMETRIC ONE-POT SYNTHESIS OF CYCLOPROPANES
    Guesmi, Ahlem
    Nouira, Wided
    Ben Hamadi, Naoufel
    MACEDONIAN JOURNAL OF CHEMISTRY AND CHEMICAL ENGINEERING, 2016, 35 (01) : 45 - 52
  • [5] SYNTHESIS OF PINACOL SILYLETHERS FROM AROMATIC-ALDEHYDES VIA ALPHA-SILOXYBENZYLIRON COMPLEXES
    VARGAS, RM
    HOSSAIN, MM
    TETRAHEDRON LETTERS, 1993, 34 (17) : 2727 - 2728
  • [6] One-pot synthesis of multisubstituted quaterphenyls and cyclopropanes
    Chang, Meng-Yang
    Chan, Chieh-Kai
    Lin, Shin-Ying
    Wu, Ming-Hao
    TETRAHEDRON, 2013, 69 (47) : 10036 - 10044
  • [7] Highly Efficient Microwave-assisted One-Pot Synthesis of Aromatic Nitriles from Aromatic Aldehydes
    P. L. Pujari
    P. V. Thorat
    A. B. Mahipal
    R. S. Bhondwe
    Russian Journal of Organic Chemistry, 2019, 55 : 702 - 706
  • [8] Highly Efficient Microwave-assisted One-Pot Synthesis of Aromatic Nitriles from Aromatic Aldehydes
    Pujari, P. L.
    Thorat, P. V.
    Mahipal, A. B.
    Bhondwe, R. S.
    RUSSIAN JOURNAL OF ORGANIC CHEMISTRY, 2019, 55 (05) : 702 - 706
  • [9] A one-pot procedure for the synthesis of iodoalkynes from aldehydes
    Michel, P
    Rassat, A
    TETRAHEDRON LETTERS, 1999, 40 (49) : 8579 - 8581
  • [10] One-pot synthesis of conjugated alkynenitriles from aldehydes
    Kim, Joong-Gon
    Lee, Eun Hwa
    Jang, Doo Ok
    TETRAHEDRON LETTERS, 2007, 48 (13) : 2299 - 2301