Crystal structure of bis(2,2 ': 6 ',2 ''-terpyridine- kappa N-3, N ', N '')nickel(II) dicyanidoaurate(I)

被引：1
|
作者：
White, Frankie [1 ]
Sykora, Richard E. [1 ]
机构：
[1] Univ S Alabama, Dept Chem, Mobile, AL 36688 USA
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2014年 / 70卷
基金：
美国国家科学基金会;
关键词：
crystal structure; terpyridine; aurophilic interaction; dicyanidoaurate;
D O I：
10.1107/S1600536814024672
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
The title compound, [Ni(C15H11N3)(2)][Au(CN)(2)](2), is an ionic compound composed of bis(2,2 ': 6 ', 2 ''-terpyridine)nickel(II) dications and dicyanidoaurate(I) anions in a 1: 2 ratio. The two tridentate terpyridine ligands define the coordination of the Ni (2+) cation, resulting in a nearly octahedral coordination sphere, although there is not any imposed crystallographic symmetry about the Ni 2+ site. The two nearly linear dicyanidoaurate(I) anions [C-Au-C = 179.0 (2) and 178.2 (2)degrees] contain a short aurophilic interaction of 3.1017 (3) angstrom. The structure does not demonstrate any pi-pi stacking. Non-classical C-H center dot center dot center dot N interactions between the cations and anions build up a three-dimensional network.
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收藏
页码：519 / +
页数：10
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