NOVEL N,N'-METHYLENE-BRIDGED METAL(II) COMPLEXES OF N,N'-METHYLENEDI(4-HYDROXY-L-PROLINE) OBTAINED FROM THE CONDENSATION OF BIS(4-HYDROXY-L-PROLINATO)METAL(II) WITH FORMALDEHYDE

被引:0
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作者
TEO, SB
TEOH, SG
NG, CH
FUN, HK
DECLERCQ, JP
机构
[1] UNIV SAINS MALAYSIA,SCH PHYS,GEORGE TOWN 11800,MALAYSIA
[2] UNIV CATHOLIQUE LOUVAIN,CHIM PHYS & CRISTALLOG LAB,B-1348 LOUVAIN,BELGIUM
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中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
The condensation of bis(4-hydroxy-L-prolinato)metal(II) (metal = zinc, cobalt, copper, nickel) with formaldehyde led to the formation of the respective metal(II) complexes of N,N'-methylenedi(4-hydroxy-L-proline), M(II)[My(OH-Pro)(2)], each of which possesses an N,N'-methylene bridge linking the coordinated 4-hydroxy-L-proline ligands. Such linkage is without precedent in the products of the reactions of chelated amino acids with aldehydes.
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页码:1447 / 1451
页数:5
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