SYNTHESIS AND PROPERTIES OF HYDROXY-TEMPO-SUBSTITUTED AND PHENOXYL-SUBSTITUTED TTF DERIVATIVES

被引：21
|
作者：
NAKATSUJI, S
SATOKI, S
SUZUKI, K
ENOKI, T
KINOSHITA, N
ANZAI, H
机构：
[1] TOKYO INST TECHNOL,FAC SCI,DEPT CHEM,MEGURO KU,TOKYO 152,JAPAN
[2] ELECTROTECH LAB,TSUKUBA,IBARAKI 305,JAPAN
来源：
SYNTHETIC METALS | 1995年 / 71卷 / 1-3期
关键词：
D O I：
10.1016/0379-6779(94)03066-F
中图分类号：
T [工业技术];
学科分类号：
08 ;
摘要：
The reaction of lithio derivative of TTF with 4-oxo-TEMPO (2,2,6,6-tetramethyl-1-piperidinyloxy) in diethylether gave hydroxy-TEMPO-substituted TTF derivative 1. Phenoxyl-substituted TTF derivative 2 was prepared from the lithio derivative of TTF with 2,6-di-t-butyl-p-benzoquinone via phenol intermediate. Each donors had moderate oxidation potentials estimated from CV measurement and gave CT complexes with several accepters as I-2, DDQ or TCNQF(4).
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收藏
页码：1819 / 1820
页数：2
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