SYNTHESIS AND CONFORMATIONAL-ANALYSIS OF 6-MEMBERED CYCLIC PHENYL PHOSPHITES

被引：14
|
作者：
GORDILLO, B
GARDUNO, C
GUADARRAMA, G
HERNANDEZ, J
机构：
[1] Departamento de Química, Centro de Investigación y de Estudios Avanzados, Instituto Politécnico National, México, D.F
来源：
JOURNAL OF ORGANIC CHEMISTRY | 1995年 / 60卷 / 16期
关键词：
D O I：
10.1021/jo00121a041
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A procedure for synthesizing potentially anancomeric equatorial phenyl phosphites (cis-l and eq-cis-2) is reported. Spectral characteristics and low-temperature NMR studies on the phenyl phosphites suggest that eq-cis-a is a system with a predominant chair conformation in solution. On the contrary, cis-l is conformationally heterogeneous.
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页码：5180 / 5185
页数：6
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