PALLADIUM-CATALYZED REGIOSELECTIVE CYCLIZATION OF UNSATURATED BROMOANILINOALKENENITRILES

被引：35
|
作者：
YANG, CC [1 ]
SUN, PJ [1 ]
FANG, JM [1 ]
机构：
[1] NATL TAIWAN UNIV,DEPT CHEM,TAIPEI 107,TAIWAN
来源：
JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1994年 / 22期
关键词：
D O I：
10.1039/c39940002629
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
alpha-(o-Bromoanilino)alkenenitriles are converted to 2-(methylamino)benzonitrile and varied gamma-carbolines by catalysis with palladium; the reactions may involve intramolecular aryl additions to the cyano group and other processes such as cyano group transposition, electrocyclisation, ethyl group transfer and oxidative aromatisation.
引用
收藏
页码：2629 / 2630
页数：2
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