SYNTHETIC STUDIES ON THAXTOMIN-A AND THAXTOMIN-B, PHYTOTOXINS ASSOCIATED WITH STREPTOMYCES-SCABIES, THE CAUSAL ORGANISM OF POTATO COMMON SCAB

被引：23
|
作者：
GELIN, J
MORTIER, J
MOYROUD, J
CHENE, A
机构：
[1] RHONE POULENC SECTEUR AGRO,CTR RECH DARGOIRE,BP 9163,F-69263 LYON 09,FRANCE
[2] RHONE POULENC AG CO,RES TRIANGLE PK,NC 27709
来源：
JOURNAL OF ORGANIC CHEMISTRY | 1993年 / 58卷 / 13期
关键词：
D O I：
10.1021/jo00065a001
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
The preliminary results of a study on the stereocontrolled racemic synthesis of thaxtomins A and B are disclosed. The synthesis features a new C-C bond-forming reaction: dilithium tetrachlorocuprate was shown to be an efficient catalyst for cross-coupling reactions of lithiated 1,4-dialkyl-2,5-piperazinedione anions with gramine methosulfate and alkyl halides.
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页码：3473 / 3475
页数：3
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