STRUCTURE OF (CYANO)(2,3,7,8,12,13,17,18-OCTAETHYLPORPHINATO)(PYRIDINE)IRON(III) CHLOROFORM SOLVATE

被引：19
|
作者：
SCHEIDT, WR [1 ]
HATANO, K [1 ]
机构：
[1] NAGOYA CITY UNIV,FAC EXPTL RES,MISUHO KU,NAGOYA,AICHI 467,JAPAN
来源：
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 1991年 / 47卷
关键词：
D O I：
10.1107/S0108270191003220
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
[Fe(C36H44N4)(CN)(C5H5N)].CHCl3, M(r) = 813.12, monoclinic, P2(1)/n, a = 10.345 (2), b = 14.748 (2), c = 27.302 (3) angstrom, beta = 92.12 (3)-degrees, V = 4162.6 angstrom 3, Z = 4, D(x) = 1.30, D(m) = 1.29 g cm-3, Mo K-alpha, lambda = 0.71073 angstrom, mu = 5.92 cm-1, F(000) = 1708, T = 293 K, R = 0.046 for 5193 unique observed [F > 3-sigma(F)] reflections. The iron(III) atom is six-coordinate with an average Fe-N(p) distance of 1.980 (4) angstrom and axial Fe-C and Fe-N distances of 1.934 (4) and 2.087 (3) angstrom, respectively.
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页码：2201 / 2203
页数：3
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