Structure, stability and permeation properties of NaA zeolite membranes for H2O/H2 and CH3OH/H2 separations

被引:25
|
作者
Lee, Sang Moon [1 ,3 ]
Xu, Nong [1 ,5 ]
Grace, John R. [1 ]
Li, Anwu [1 ,2 ]
Lim, C. Jim [1 ]
Kim, Sung Su [3 ]
Fotovat, Farzam [1 ]
Schaadt, Achim [4 ]
White, Robin J. [4 ]
机构
[1] Univ British Columbia, Dept Chem & Biol Engn, 2360 East Mall, Vancouver, BC V6T 1Z3, Canada
[2] NORAM Engn & Constructors Ltd, Suite 1800-200, Vancouver, BC V6C 1S4, Canada
[3] Kyonggi Univ, Dept Environm Energy Engn, 94 San, Suwon 442760, Gyeonggi Do, South Korea
[4] Fraunhofer Inst Solar Energy Syst ISE, Heidenhofstr 2, D-79110 Freiburg, Germany
[5] Mem Univ Newfoundland, Fac Engn & Appl Sci, St John, NF, Canada
关键词
NaA zeolite; Membrane; Structure; Stability; Separation factor; Sodalite; METHANOL SYNTHESIS; HYDROTHERMAL SYNTHESIS; SYNTHESIS PARAMETERS; COMPOSITE MEMBRANE; THERMAL-STABILITY; GAS-MIXTURES; TEMPERATURE; PERFORMANCE; REACTOR; DEHYDRATION;
D O I
10.1016/j.jeurceramsoc.2017.08.012
中图分类号
TQ174 [陶瓷工业]; TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
NaA zeolite membranes were synthesised in the secondary growth hydrothermal method based on the seeding of the inner surface of a ceramic a-alumina tube. The impacts' of crystallisation time and zeolite precursor concentration (in H2O) were investigated. The structure and stability of the prepared NaA zeolite membranes were also investigated with operating temperatures, times and pressures. The results indicate that the optimal synthesis gel molar composition was 3Na(2)O: 2SiO2: Al2O3: 200H(2)0. This led to cubic-shaped NaA zeolite which showed good stability. The optimal NaA zeolite membrane had H2O and CH3OH fluxes of 2.77 and 0.19 kg/m(2)h, with H2O/H-2 and CH3OH/H-2 separation factors of and 0.09 at a temperature of 30 degrees C. The NaA zeolite membrane had high thermal stability, but poor separation performance at high temperature (240 degrees C). The results suggested that the H-2 permeation flux is significantly influenced by preferential adsorption of vapour in the NaA zeolite membrane.
引用
收藏
页码:211 / 219
页数:9
相关论文
共 50 条
  • [21] [30]metallacrown-10 compounds:: [Mn(C14H9N2O3)(CH3OH)]10•5CH2Cl2•6 CH3OH•H2O and [Fe(C14H9N2O3)(CH3OH)]10•3 CH2Cl2•12.5 CH3OH•5 H2O
    Liu, SX
    Lin, S
    Lin, BZ
    Lin, CC
    Huang, JQ
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2001, 40 (06) : 1084 - +
  • [22] Synthesis, crystal structure and magnetic properties of a novel complex [Cu(NIT2Py)(PDA)(H2O)]•(CH3OH)(H2O)
    Zhang, CX
    Liu, ZL
    Liao, DZ
    Jiang, ZH
    Yan, SP
    JOURNAL OF MOLECULAR STRUCTURE, 2003, 650 (1-3) : 21 - 26
  • [23] SPECTROSCOPIC STUDIES CONCERNING STRUCTURE AND THERMODYNAMIC BEHAVIOUR OF H2O CH3OH AND C2H5OH
    LUCK, WAP
    DISCUSSIONS OF THE FARADAY SOCIETY, 1967, (43): : 115 - &
  • [24] Vibrational quenching of H2O in collision with H2
    Faure, A
    Wiesenfeld, L
    Wernli, M
    Valiron, P
    PROCEEDINGS OF THE DUSTY AND MOLECULAR UNIVERSE: A PRELUDE TO HERSCHEL AND ALMA, 2005, 577 : 361 - 362
  • [25] Computational Astrochemistry: H2O - H2 collisions
    Zoltowski, Michal
    Zuchowski, Piotr
    Karska, Agata
    XXXVIII POLISH ASTRONOMICAL SOCIETY MEETING, 2018, 7 : 181 - 183
  • [26] Application of one-dimensional semiclassical transition state theory to the CH3OH + H (sic) CH2OH/CH3O + H2 reactions
    Shan, Xiao
    Clary, David C.
    PHILOSOPHICAL TRANSACTIONS OF THE ROYAL SOCIETY A-MATHEMATICAL PHYSICAL AND ENGINEERING SCIENCES, 2018, 376 (2115):
  • [27] Selective photocatalytic reduction of CO2 by H2O/H2 to CH4 and CH3OH over Cu-promoted In2O3/TiO2 nanocatalyst
    Tahir, Muhammad
    Tahir, Beenish
    Amin, Nor Aishah Saidina
    Alias, Hajar
    APPLIED SURFACE SCIENCE, 2016, 389 : 46 - 55
  • [28] CH3OH、CO2、H2体系汽液平衡研究
    宋文濂
    北京化工学院学报, 1987, (01) : 45 - 55
  • [29] Hydrothermal Synthesis,Crystal Structure and Thermal Stability Properties of the Complex [Cd2(phen)2(C14H11O3)4(CH3CH2OH)]·(CH3OH)·(H2O)
    李昶红
    谢和平
    谭雄文
    杨颖群
    李薇
    结构化学, 2010, 29 (09) : 1317 - 1320
  • [30] REACTIONS INVOLVING H2 O2 OH H AND O
    不详
    PYRODYNAMIC, 1965, 2 (2-3): : 197 - &