EXCESS MOLAR VOLUMES OF (1,1,3,3-TETRAMETHYLUREA+AN ALKAN-1-OL) AT THE TEMPERATURE 298.15-K

被引:17
|
作者
UOSAKI, Y
HAMAGUCHI, T
MORIYOSHI, T
机构
[1] Department of Chemical Science and Technology, Faculty of Engineering, University of Tokushima, Tokushima
来源
JOURNAL OF CHEMICAL THERMODYNAMICS | 1992年 / 24卷 / 05期
关键词
D O I
10.1016/S0021-9614(05)80124-7
中图分类号
O414.1 [热力学];
学科分类号
摘要
Excess molar volumes VEm for (1,1,3,3-tetramethylurea + methanol or ethanol or propan-1-ol or butan-1-ol) have been obtained from density measurements at the temperature 298.15 K over the whole mole-fraction range. The excess molar volumes for all the mixtures are negative and decrease in magnitude with an increase of alkyl-chain length of the alkan-1-ol molecule. The VEm values for (1,1,3,3-tetramethylurea + an alkan-1-ol) are compared with those reported for (N,N-dimethylacetamide + an alkan-1-ol). © 1992 Academic Press Limited All rights reserved.
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页码:549 / 554
页数:6
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