CHEMICAL-DEPENDENCE OF CORE-LEVEL LINEWIDTHS AND LIGAND-FIELD SPLITTINGS - HIGH-RESOLUTION CORE-LEVEL PHOTOELECTRON-SPECTRA OF I-4D LEVELS

被引：37
|
作者：
CUTLER, JN
BANCROFT, GM
SUTHERLAND, DG
TAN, KH
机构：
[1] UNIV WESTERN ONTARIO,DEPT CHEM,LONDON N6A 5B7,ONTARIO,CANADA
[2] UNIV WESTERN ONTARIO,DEPT CHEM PHYS,LONDON N6A 5B7,ONTARIO,CANADA
[3] UNIV WISCONSIN,CTR SYNCHROTRON RADIAT,CANADIAN SYNCHROTRON RADIAT FACIL,MADISON,WI 53706
来源：
PHYSICAL REVIEW LETTERS | 1991年 / 67卷 / 12期
关键词：
D O I：
10.1103/PhysRevLett.67.1531
中图分类号：
O4 [物理学];
学科分类号：
0702 ;
摘要：
High-resolution I 4d photoelectron spectra (total instrumental resolution < 0.06 eV) of several iodine molecules, ICl, IBr, I2, and CH2I2, are reported. The inherent I 4d Lorentzian linewidths increase in the above order, due to the decrease in electronegativity of the moieties bound to I. The ligand-field splitting as measured by the C2(0) crystal-field term decreases in the above order, and correlates extremely well with the electric-field gradient measured by I-129 quadrupole splittings.
引用
收藏
页码：1531 / 1534
页数：4
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