NONREVERSIBLE ADSORPTION OF DIVALENT METAL-IONS (MN-II, CO-II NI-II CU-II AND PB-II) ONTO GOETHITE - EFFECTS OF ACIDIFICATION, FE-II ADDITION, AND PICOLINIC-ACID ADDITION

被引：206

作者：

COUGHLIN, BR ^{[1
]}

STONE, AT ^{[1
]}

机构：

[1] JOHNS HOPKINS UNIV, GWC WHITING SCH ENGN, DEPT GEOG & ENVIRONM ENGN, BALTIMORE, MD 21218 USA

来源：

ENVIRONMENTAL SCIENCE & TECHNOLOGY | 1995年 / 29卷 / 09期

关键词：

D O I：

10.1021/es00009a042

中图分类号：

X [环境科学、安全科学];

学科分类号：

08 ; 0830 ;

摘要：

Differences in the coordination chemistry of divalent metal ions affect their adsorption onto goethite (alpha-FeOOH) surfaces and their subsequent release by acidification, Fe-II addition, and picolinic acid addition. Equilibrium constants for adsorption onto FeOOH (goethite) decrease in the order: Cu-II > Pb-II > Ni-II approximate to Co-II > Mn-II. Equilibrium constants for picolinic acid complexation follow the Irving-Williams series; complex formation with Pb-II and Mn-II is nearly negligible. Divalent metal ion release 24 h following acidification or picolinic acid addition is typically less than the amount predicted using an equilibrium speciation model, indicating adsorption/desorption hysteresis. Experiments performed under strict exclusion of O-2 reveal a slight increase in Co-II, Ni-II, and Cu-II adsorption upon the addition of 1000 mu M Fe-II. Fe-II interferes with the ability of picolinic acid to cause divalent metal ion release.

引用

页码：2445 / 2455

页数：11

共 50 条

[31] SEPARATION OF Fe (III), Cr(III), Cu(II), Ni(II), Co(II), AND Pb(II) METAL IONS USING POLY(EUGENYL OXYACETIC ACID) AS AN ION CARRIER BY A LIQUID MEMBRANE TRANSPORT METHOD
Harimu, La
Matsjeh, Sabirin
Siswanta, Dwi
Santosa, Sri Juari
INDONESIAN JOURNAL OF CHEMISTRY, 2010, 10 (01) : 69 - 74
[32] ORGANIC-ACID SOLUTIONS IN THE CHROMATOGRAPHY OF INORGANIC-IONS .7. CATION-EXCHANGE OF MG(II), CA(II), SR(II), BA(II), MN(II), CD(II), CO(II), NI(II), ZN(II), CU(II) AND FE(III) IN SUCCINATE MEDIA
DADONE, A
BAFFI, F
FRACHE, R
MAZZUCOTELLI, A
CHROMATOGRAPHIA, 1979, 12 (01) : 38 - 43
[33] Physicochemical investigations, biological studies of the Cr(III), Mn(II), Fe(III), Co(II), Ni(II), Cu(II), Zn(II), Cd(II), Hg(II) and UO2(VI) complexes of picolinic acid hydrazide derivative: A combined experimental and computational approach
Yousef, T. A.
Abu El-Reash, G. M.
Abu AL-Zahab, M.
Safaan, M. A. A.
JOURNAL OF MOLECULAR STRUCTURE, 2019, 1197 : 564 - 575
[34] METAL-COMPLEXES WITH TETRAPYRROLE LIGANDS .48. VILSMEIER FORMYLATION OF METAL PORPHYRINS OF CO-II, NI-II, PD-II, PT-II, CU-II, ZN-II, CO-III, CR-III, MN-III, FE-III, AL-III, SI-IV, AND PT-IV AND ITS DEPENDENCE UPON THE CENTRAL METAL
BUCHLER, JW
DREHER, C
HERGET, G
LIEBIGS ANNALEN DER CHEMIE, 1988, (01): : 43 - 54
[35] SEPARATION OF METAL VALUES FROM SULFURIC ACID LEACH SOLUTION OF MANGANESE NODULE. COPRECIPITATION OF Mn (II), Cu (II), Ni (II), AND Co (II) IONS WITH FERRIC HYDROXIDE.
Fujii, Yujiro
Mizota, Tadato
Kono, Yoshimi
Shirozoe, Masahiro
Murakami, Fumio
Nihon Kogyokaishi, 1985, 101 (1171): : 531 - 536
[36] COMPLEXATION REACTION OF METAL-IONS WITH PEPTIDE SYSTEMS .11. POTENTIOMETRIC STUDY OF COMPLEX-FORMATION BETWEEN NI(II), CO(II), CU(II), ZN(II), CD(II) AND PB(II) AND N-BENZOYL-GLYCYL-L-LEUCINE
SANDHU, RS
KUMAR, R
JOURNAL OF THE INDIAN CHEMICAL SOCIETY, 1981, 58 (07) : 659 - 661
[37] SYNTHESIS OF POLYEUGENYL OXYACETIC ACID AS A CARRIER TO SEPARATE HEAVY METAL ION Fe (III), Cr(III), Cu(II), Ni(II), Co(II), AND Pb(II) THAT USING SOLVENT EXTRACTION METHOD
Harimu, La
Matsjeh, Sabirin
Siswanta, Dwi
Santosa, Juari
INDONESIAN JOURNAL OF CHEMISTRY, 2009, 9 (02) : 261 - 266
[38] ORGANIC-ACID SOLUTIONS IN CHROMATOGRAPHY OF INORGANIC-IONS .4. CATION-EXCHANGE OF MN(II), CD(II), CO(II), NI(II), CU(II), AL(III) AND FE(III) IN TARTRATE MEDIA
DADONE, A
BAFFI, F
FRACHE, R
TALANTA, 1976, 23 (08) : 593 - 595
[39] SYNTHESIS AND REACTIVITY TOWARDS DIOXYGEN OF A SERIES OF 5-COORDINATED COMPLEXES BETWEEN N,N'-(3,3'-DIPROPYLMETHYLAMINE)BIS(2-HYDROXY-1-NAPHTHYLIDENAMINE) AND THE METAL-IONS MN(II), FE(II), CO(II), NI(II) AND CU(II)
CINI, R
ZANELLO, P
CINQUANTINI, A
COLLIGIANI, A
PINZINO, C
VALENTINI, G
INORGANICA CHIMICA ACTA-BIOINORGANIC CHEMISTRY, 1983, 79 (1-6): : 203 - 204
[40] STUDY OF COMPLEX-COMPOUNDS OF N-BENZENESULFONYLGLYCINE WITH SOME METAL-IONS .22. FORMATION-CONSTANTS OF CU(II), ZN(II), CO(II), NI(II) AND CD(II) CHELATES OF BETA-BENZENESULPHONAMIDOSUCCINAMIC ACID
GHOSH, NN
MOKHOPADHYAY, SK
INDIAN JOURNAL OF CHEMISTRY SECTION A-INORGANIC BIO-INORGANIC PHYSICAL THEORETICAL & ANALYTICAL CHEMISTRY, 1978, 16 (02): : 152 - 155

← 1 2 3 4 5 →