EPR of CH2: A substantially bent and partially rotating ground state triplet

被引：160

作者：

Wasserman, E. ^{[1
,2
]}

Yager, W. A. ^{[2
]}

Kuck, V. J. ^{[2
]}

机构：

[1] Bell Telephone Labs Inc, Murray Hill, NJ 07974 USA

[2] Rutgers State Univ, Sch Chem, New Brunswick, NJ 08903 USA

来源：

CHEMICAL PHYSICS LETTERS | 1970年 / 7卷 / 04期

关键词：

D O I：

10.1016/0009-2614(70)80320-7

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

EPR spcetra assignable to ground state triple : CH2 have been observed on photolysis of diazomethane and diazirene at 4 degrees K. Two different systems ascribable to to different crystalline sites are observed with each precursor. Analysis of the spectra shows that the long axis of the molecule is largely fixed while rotation about that is almost free. The most probable value of the HCH angle its 136 degrees, in good agreement with most theoretical calculations and smaller than some values compatible with the electronic spectrum.

引用

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页码：409 / 413

页数：5

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