EFFECT OF URANIUM(VI) ON EXTRACTION OF TECHNETIUM AND ZIRCONIUM(IV) BY TRIBUTYL-PHOSPHATE

被引:0
|
作者
AKOPOV, GA
KRANITSYN, AP
TSARENKO, AF
机构
来源
SOVIET RADIOCHEMISTRY | 1989年 / 31卷 / 06期
关键词
D O I
暂无
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
In this paper, the mechanism of extraction of technetium in the 30%-tributyl phosphate (TBP)-solution-in-dodecane-nitric acid-uranium-zirconium system was examined. It was shown that the extraction behavior of technetium is described satisfactorily by a mechanism of ligand exchange of pertechnetate and nitrate ions in uranium and zirconium solvates.
引用
收藏
页码:681 / 685
页数:5
相关论文
共 50 条
  • [31] TITANIUM (III) EXTRACTION WITH TRIBUTYL-PHOSPHATE (TBP)
    TEDESCO, PH
    MARTINEZ, J
    [J]. ANALES DE LA ASOCIACION QUIMICA ARGENTINA, 1977, 65 (02): : 115 - 120
  • [32] EXTRACTION OF ZIRCONIUM THIOCYANATES IN TRIBUTYL-PHOSPHATE FROM SULFURIC ACID SOLUTIONS OF VARIOUS ORIGINS
    SHOSTENKO, NA
    YAGODIN, GA
    NEKHAMKIN, LG
    TSYLOV, YA
    [J]. ZHURNAL NEORGANICHESKOI KHIMII, 1976, 21 (01): : 263 - 265
  • [33] TRIBUTYL-PHOSPHATE EXTRACTION OF TANTALUM THIOCYANATE COMPLEXES
    SYCH, AM
    DUGEL, NG
    [J]. ZHURNAL NEORGANICHESKOI KHIMII, 1977, 22 (02): : 448 - 452
  • [34] REVERSED PHASE EXTRACTION CHROMATOGRAPHY OF MOLYBDENUM(VI) WITH TRIBUTYL-PHOSPHATE ON SILICA-GEL
    BHOSALE, SN
    KHOPKAR, SM
    [J]. INDIAN JOURNAL OF CHEMISTRY SECTION A-INORGANIC BIO-INORGANIC PHYSICAL THEORETICAL & ANALYTICAL CHEMISTRY, 1982, 21 (02): : 147 - 149
  • [35] TRIBUTYL-PHOSPHATE EXTRACTION OF TITANIUM THIOCYANATE COMPLEXES
    SYCH, AM
    GARBUZ, VV
    [J]. ZHURNAL NEORGANICHESKOI KHIMII, 1974, 19 (07): : 1908 - 1913
  • [36] MOLYBDENUM(VI) EXTRACTION FROM CONCENTRATED SULFURIC-ACID SOLUTIONS BY TRIBUTYL-PHOSPHATE
    KOPACH, S
    [J]. ZHURNAL NEORGANICHESKOI KHIMII, 1974, 19 (03): : 794 - 799
  • [37] EXTRACTION OF URANIUM(VI) BY DI-(2-ETHYLHEXYL)-PHOSPHORIC ACID TRIBUTYL-PHOSPHATE AND TRIOCTYL PHOSPHINE OXIDE GELS
    SHAKIR, K
    BEHEIR, SG
    [J]. CHIMIA, 1979, 33 (06) : 192 - 195
  • [38] STUDY ON COMPETITION BETWEEN NITRIC-ACID, NITROUS-ACID AND URANIUM(VI) AND THORIUM(IV) NITRATES IN EXTRACTIONS BY TRIBUTYL-PHOSPHATE
    MARIN, B
    SELLIER, JY
    GOURISSE, D
    [J]. JOURNAL OF INORGANIC & NUCLEAR CHEMISTRY, 1974, 36 (06): : 1377 - 1380
  • [39] REFINING OF ZIRCONIUM BY TRIBUTYL-PHOSPHATE IN PULSED PACKED-COLUMNS
    ELYAMANI, IS
    ELALEIM, FAA
    [J]. HYDROMETALLURGY, 1984, 13 (02) : 213 - 220
  • [40] SEPARATION OF ZIRCONIUM AND HAFNIUM BY SOLID EXTRACTANT BASED ON TRIBUTYL-PHOSPHATE
    KOROVIN, VY
    YAGODIN, GA
    SAVELEVA, VI
    [J]. RUSSIAN JOURNAL OF APPLIED CHEMISTRY, 1994, 67 (05) : 678 - 680