STATISTICAL-MECHANICS BASIS OF MACLEODS FORMULA

被引：29
|
作者：
BOUDHHIR, ME [1 ]
MANSOORI, GA [1 ]
机构：
[1] UNIV ILLINOIS,DEPT CHEM ENGN,BOX 4348,CHICAGO,IL 60680
来源：
JOURNAL OF PHYSICAL CHEMISTRY | 1990年 / 94卷 / 21期
关键词：
D O I：
10.1021/j100384a068
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
In this work the theoretical basis for the famous formula of Macleod, relating the surface tension of a liquid in equilibrium with its own vapor to the one-particle densities in the two phases of the system, is derived. Using the statistical-mechanical definition of the surface tension, it is proved that this property is, at the first approximation, given by the Macleod formula. © 1990 American Chemical Society.
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页码：8362 / 8364
页数：3
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