STATISTICAL-MECHANICS BASIS OF MACLEODS FORMULA

被引：29

作者：

BOUDHHIR, ME ^{[1
]}

MANSOORI, GA ^{[1
]}

机构：

[1] UNIV ILLINOIS,DEPT CHEM ENGN,BOX 4348,CHICAGO,IL 60680

来源：

JOURNAL OF PHYSICAL CHEMISTRY | 1990年 / 94卷 / 21期

关键词：

D O I：

10.1021/j100384a068

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

In this work the theoretical basis for the famous formula of Macleod, relating the surface tension of a liquid in equilibrium with its own vapor to the one-particle densities in the two phases of the system, is derived. Using the statistical-mechanical definition of the surface tension, it is proved that this property is, at the first approximation, given by the Macleod formula. © 1990 American Chemical Society.

引用

页码：8362 / 8364

页数：3

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