EFFECT OF CATALYST ON THE CURING OF TETRAFUNCTIONAL EPOXY-RESIN FORMULATIONS

被引:14
|
作者
JAGADEESH, KS
SIDDARAMAIAH
机构
[1] Department of Polymer Science and Technology, S. J. College of Engineering, Mysore
关键词
D O I
10.1002/app.1991.070430807
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
Cure kinetics of tetraglycidyl 4,4'-diaminodiphenyl methane resin formulations with diaminodiphenylsulfone as hardener and borontrifluoride-ethylamine adduct as accelerator has been studied by differential scanning calorimetry (DSC) technique both dynamically and isothermally. The DSC scans show multiple exotherm peaks, indicating the complex nature of reaction. The curing exotherms obtained have been analysed to derive the kinetic parameters associated with the curing process. The heat of reaction shows a decreasing trend with increasing catalyst concentration.
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页码:1459 / 1465
页数:7
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