PALLADIUM(II)-CATALYZED OXIDATION OF CARBON-CARBON DOUBLE-BONDS OF ALLYLIC COMPOUNDS WITH MOLECULAR-OXYGEN - REGIOSELECTIVE FORMATION OF ALDEHYDES

被引：55

作者：

HOSOKAWA, T

AOKI, S

TAKANO, M

NAKAHIRA, T

YOSHIDA, Y

MURAHASHI, SI

机构：

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1991年 / 21期

关键词：

D O I：

10.1039/c39910001559

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Treatment of N-allylamides 1a-c and lactams 1d-f with molecular oxygen in the presence of [PdCl2(MeCN)2]-CuCl catalyst in anhydrous 1,2-dichloroethane containing hexamethylphosphoric triamide gives the corresponding aldehydes 2 regioselectively, while methyl ketones 3 become the major products in the presence of water.

引用

页码：1559 / 1560

页数：2

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