EXPERIMENTS DIRECTED TOWARDS THE SYNTHESIS OF ANTHRACYCLINONES .27. TRANSFORMATIONS OF 2,3-BISALKYNYL AND 2,3-BISALKENYL ANTHRAQUINONES

被引：9

作者：

BONIFACE, PJ ^{[1
]}

CAMBIE, RC ^{[1
]}

HIGGS, C ^{[1
]}

RUTLEDGE, PS ^{[1
]}

WOODGATE, PD ^{[1
]}

机构：

[1] UNIV AUCKLAND,DEPT CHEM,AUCKLAND,NEW ZEALAND

来源：

AUSTRALIAN JOURNAL OF CHEMISTRY | 1995年 / 48卷 / 06期

关键词：

D O I：

10.1071/CH9951089

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

2,3-Bisalkynyl anthraquinones have been synthesized and their behaviour under Bergman-type cyclization conditions has been studied. Cyclization reactions of 2,3-bis(propenyl)anthraquinones yield a number of products, mechanisms for the formation of which are proposed. An attempt to elaborate an A-ring from the 2,3-allyl side chains of the bisallylated anthraquinone (32) is reported.

引用

页码：1089 / 1106

页数：18

共 50 条

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