CARBONYLATION OF ARYLIODIDES IN THE PRESENCE OF A PALLADIUM CATALYST WITH OLIGOMERIC LIGANDS

被引:0
|
作者
KARAKHANOV, EA
RUNOVA, YA
NEIMEROVETS, YB
BEREZKIN, GV
ROZANTSEVA, LE
机构
[1] Moscow State Univ, Moscow, Russia
关键词
D O I
暂无
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
A homogeneous, easily regenerated catalyst with oligomeric ethylene ligands containing end diphenylphosphine groups has been synthesized. It has been shown that bis(polyethylene-diphenylphosphine)palladium(II)chloride is an effective carbonylation catalyst and can be used repeatedly. For the case of the carbonylation of a model compound - iodobenzene, the optimum conditions of the reaction have been determined, and the carbonylation of a number of substituted forms of aryliodides has been carried out.
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页码:192 / 198
页数:7
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