SELECTIVITY IN THE PROPARGYLATION OF POLYFUNCTIONAL AMINES BY (PROPARGYLIUM)-CO2(CO)6+ AND (PROPARGYLIUM)-(C5H5)2MO2(CO)4+

被引：29

作者：

GRUSELLE, M ^{[1
]}

PHILOMIN, V ^{[1
]}

CHAMINANT, F ^{[1
]}

JAOUEN, G ^{[1
]}

NICHOLAS, KM ^{[1
]}

机构：

[1] UNIV OKLAHOMA, DEPT CHEM & BIOCHEM, NORMAN, OK 73019 USA

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1990年 / 399卷 / 03期

基金：

美国国家卫生研究院;

关键词：

D O I：

10.1016/0022-328X(90)85496-L

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

[(HC = CCH2)Co2(CO)6]BF4 (1) and [(HC = CCH2)Mo2(C5H5)2(CO)4]BF4 (2) react with primary and secondary amines in CH2Cl2 solution. In the case of primary amines, the products of mono and dialkylation are obtained. The more stable (less reactive) molybdenum complexes can be employed to alkylate amines in a protic, two-phase medium. The results are interpreted mechanistically and shown to dependent on the thermodynamic stability of the metal-stabilized carbocation.

引用

页码：317 / 326

页数：10

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