X-RAY-EMISSION SPECTRA AND VALENCE BAND-STRUCTURE OF THE 3D-TRANSITION METAL-OXIDES

被引：17

作者：

GALAKHOV, VR

BUTORIN, SM

KURMAEV, EZ

KOROTIN, MA

机构：

[1] Institute of Metal Physics, Academy of Sciences, the USSR, Sverdlovsk

来源：

PHYSICA B | 1991年 / 168卷 / 03期

关键词：

D O I：

10.1016/0921-4526(91)90666-3

中图分类号：

O469 [凝聚态物理学];

学科分类号：

070205 ;

摘要：

X-ray emission oxygen K-alpha and 3d transition metal L-alpha spectra for MnO, FeO, CoO, NiO, and CuO have been compared in the same energy scale by using Me 2p and O 1s binding energies. In the valence band of CuO the so-called d-p resonance between Cu 3d and O 2p states was observed. The 3d metal L-alpha-spectra for these oxides reveal both 3d(n)L and 3d(n-1) electron configurations. The 3d transition metal oxides have been proved to be insulators with a ligand-to-metal charge transfer. Maximum values of the charge transfer are for CuO and NiO.

引用

页码：163 / 169

页数：7

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