ON THE IMPORTANCE OF SPECIFIC SOLVENT EFFECTS IN ELECTRON-TRANSFER REACTIONS

被引：15
|
作者：
MOYA, ML [1 ]
SANCHEZ, F [1 ]
BURGESS, J [1 ]
机构：
[1] UNIV LEICESTER,DEPT CHEM,LEICESTER LE1 7RH,ENGLAND
来源：
INTERNATIONAL JOURNAL OF CHEMICAL KINETICS | 1993年 / 25卷 / 11期
关键词：
D O I：
10.1002/kin.550251103
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The intramolecular electron transfer reaction within the binuclear complex formed between tetraamminepyrazinecarboxylatocobalt(III) and aquopentacyanoferrate(II) ions is studied in various binary aqueous media at different temperatures. Results could not be explained on the basis of a primitive model. Experimental data were fitted by using a multiparameter regression which shows the important role played by specific interactions on reactivity. (C) 1993 John Wiley & Sons, Inc.
引用
收藏
页码：891 / 899
页数：9
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