NUCLEOPHILIC-ADDITION OF PHOSPHINE TO ARYLETHENES AND HETARYLETHENES - A CONVENIENT SYNTHESIS OF BIS(2-ARYLALKYL)PHOSPHINE AND BIS(2-HETARALKYL)PHOSPHINE

被引:112
|
作者
TROFIMOV, BA [1 ]
BRANDSMA, L [1 ]
ARBUZOVA, SN [1 ]
MALYSHEVA, SF [1 ]
GUSAROVA, NK [1 ]
机构
[1] UNIV UTRECHT,DEBYE INST,DEPT ORGAN CHEM,3584 CH UTRECHT,NETHERLANDS
关键词
D O I
10.1016/S0040-4039(00)78365-1
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
A number of secondary phosphines [RCH(R')CH2]2PH (R = aryl or hetaryl, R' = H or Me) have been obtained in good yields by introducing phosphine at normal pressure into a mixture of the alkenes R(R')C=CH2, potassium hydroxide and dimethylsulfoxide.
引用
收藏
页码:7647 / 7650
页数:4
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